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Laboratory of Rare Earth Catalysis

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Synthesis, Self-Assembly, and Drug-Loading Capacity of Well-Defined Cyclodextrin-Centered Drug-Conjugated Amphiphilic A(14)B(7) Miktoarm Star Copolymers Based on Poly(epsilon-caprolactone) and Poly(ethylene glycol)
Gou, P. F., W. P. Zhu,*, Z. Q. Shen
 Biomacromolecules 11(4): 934-943.

   Novel drug-conjugated amphiphilic A(14)B(7) miktoarm star copolymers composed of 14 poly(E-caprolactone) (PCL) arms and 7 poly(ethylene glycol) (PEG) arms with beta-cyclodextrin (beta-CD) as core moiety were synthesized by the combination of controlled ring-opening polymerization (CROP) and "click" chemistry.

 


 

Synthesis, Self-Assembly and Drug-Loading Capacity of Well-Defined Drug-Conjugated Amphiphilic A(2)B(2) Type Miktoarrn Star Copolymers Based on Poly(epsilon-caprolactone) and Poly(ethylene glycol)
Peng-Fei Gou, Wei-Pu Zhu *, Ning Xu, Zhi-Quan Shen *
Journal of Polymer Science Part B: Polymer Physics  Volume 47  Issue 24, Pages 6962 - 6976

    Well-defined drug-conjugated amphiphilic A(2)B(2) miktoarm star copolymers [(PCL)(2)-(PEG)(2)-D] were prepared by the combination of controlled ring-opening polymerization (CROP) and "click" reaction strategy

 


Synthesis and Characterization of Macroporous Silica Modified with Optically Active Poly[N-(oxazolinylphenyl)acrylamide] Derivatives for Potential Application as Chiral Stationary Phases
Y. Tian, W. Lu, Y. Che, L. B. Shen, L. M. Jiang *, Z. Q. Shen
Journal of Applied Polymer Science Volume 115  Issue 2, Pages 999 - 1007

   Enantiopure acrylamide derivatives, (S)-N-[o-(4-methyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]acrylamide and (R)-N-[o-(4-phenyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]acrylamide, were synthesized through the acylation of chiral 2-oxazolinylanilines.

 


 

Fabrication of Magnetic Thin Films by a Layer-by-Layer Self-Assembly Approach
Weihong Lin, Weilin Sun*, Jun Yang, Qihang Sun and Zhiquan Shen 
J. Phys. Chem. C, 2009, 113 (39), pp 16884–16895

   A series of multilayer films, which were fabricated via layer-by-layer self-assembly with the polymer PMPMA and the transition metal neutralized poly(styrene 4-sulfonate) (PSSNi or PSSCu) on thin plastic substrate polyethylene film (PE), were described.

 

 

 

  

    The Rare Earth Catalysis group members include 3 professors, 3 associate professors and currently 32 graduate students. The group leader is Prof. Zhiquan Shen, an academician of the Chinese Academy of Science.
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