孙维林教授

日期:2009-06-17 10:10

 

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孙维林 博士

 

教授/博士生导师

浙江大学高分子科学研究所

电话/传真:86-571-87953727

电子邮箱:opl_sunwl@emb.zju.edu.cn

邮编:310027

地址:浙江 杭州 浙江大学玉泉校区高分子大楼

孙维林,博士、教授、博士生导师。专长:高分子化学、芳杂环高分子合成、导电和磁性高分子材料制备、稀土配位催化聚合。任中国化学会会员,浙江省化学会理事,中国化工学会会员,中国微量元素与健康研究会浙江省分会常务理事。曾担任“863高性能结构材料技术主题“十五”第二批课题复审答辩会”,第五届国家自然科学基金评审委员会评审专家等国家级专题评审专家。
1957年9月出生于浙江省临海市。1979年8月杭州大学化学系毕业, 1985年9月~1988年7月于杭州大学化学系攻读硕士学位,师从张孙玮教授,从事有机试剂的合成及其在分析化学中应用研究,医药中间体合成研究,曾获1990年浙江省科技进步奖三等奖。1991年9月~1994年8月于浙江大学攻读博士学位,师从沈之荃院士,从事稀土催化剂开环聚合及功能高分子研究,1994年8月获理学博士。1994年8月~1996年8月于中科院化学研究所从事博士后研究,师从卢凤才教授,主要从事芳杂环高分子的合成及性能研究,曾获化学研究所95年度优秀青年科技奖。1996年8月出站后引进到浙江大学高分子科学及材料研究所工作。2001年赴日本广岛大学化学系访问,与Yasuda教授合作研究芳杂环稀土催化剂,2002年赴加拿大国家研究中心(NRC)化工和环境研究所访问研究,与Day教授合作开展芳杂环高分子发光材料合成研究。

      目前主要从事稀土配位催化聚合和芳杂环高分子及其软磁材料基础研究,近年来承担国家“973”子课题、国家自然科学基金重点、国家自然科学基金、横向合作等研究项目10余项,分别在《Macromolecules, Chem. Commun. 》,《Journal of Physical Chemistry C,Journal of Polymer Science, Part A: Polymer Chemistry,Macromol. Rapid. Commun., J. of  Biomedi. Mat. Res.》,《Polymer,J.of Appl. Polym.Sci,科学通报》,《高等学校化学学报》,《高分子学报》,《分析化学》,《化学通报》等国内外学术刊物上发表学术论文100余篇。

荣誉

Member of Chinese Chemical Society

Member of Chinese Chemical Engineering Society

Member of the 10th Committee of Chemistry Experts of National Natural Science Foundation of China (2004-2006)

Member of the 4th Committee of Polymer Science and Engineering State Key Laboratory, Sichuan University

Key Personnel of National Key Basic Research Development Program

Winner of Pao Yue-Kong Senior Visiting Fellowship (2002)

Member of Zhejiang Province New Century 151 Talent Project and Staff
 
承担课题

1.    Studies on soft ferromagnetic materials of novel aromatic heterocyclic polymer.

2.  Preparation of soft ferromagnetic materials of aromatic heterocyclic polymer chelating rare earths and their magnetic mechanism.
 
专利

1.    Sun, Weilin; Lin, Weihong; Yang, Jun; Shen, Zhiquan. Pyridine ring-containing polymer, its complex magnetic thin film material and preparation thereof. CN 101709099. 2010.

2.    Sun, Weilin; Zhang, Lei; Ni, Xufeng; Shen, Zhiquan. Preparation of aromatic heterocyclic Schiff base rare earth compound as polymerization catalysts. CN 101041141. 2007.     

3.    Sun, Weilin; Lin, Weihong; Yang, Jun; Shen, Zhiquan. Method for preparing bithiazole supermolecule and its magnetic chelate material. CN 1876690. 2006.

4.    Sun, Weilin; Lin, Weihong; Yang, Jun; Shen, Zhiquan. Method for preparing 2,2'-diamino-4,4'-bithiazole transition metal chelate and its supermolecular magnetic material. CN 1876651. 2006.

5.    Sun, Weilin; Zhu, Lutong. High-water-content superabsorbent polymer gels as sprayable fire extinguishing compositions. CN 1557516. 2004.

6.  Sun, Weilin; Tang, Jianbin; Shen, Zhiquan. Poly[4,4'-(2,2'-bithiazole)] high polymer and its chelate as magnetic material and preparation process. CN 1487004. 2004. 

 

主要研究方向

1.    Preparation and the properties of conductive and soft ferromagnetic polymers.

2.  Synthesis and structural study of novel polyamides, polyimides and poly-schiff base containing bisthiazole ring.

 

近期论文

1.    Wu, Guangming; Liu, Jiachu; Sun, Weilin*; Shen, Zhiquan; Ni, Xufeng.   Ring-opening polymerization of .vepsiln.-caprolactone by a new yttrium complex: Y[2,2'-ethylidene-bis(4,6-di-tert-butylphenoxy)]2(ethylene glycol dimethyl ether)Na(ethylene glycol dimethyl ether)3. Polymer International, 2010, 59(4), 431-436.

2.    Lin, Weihong; Sun, Weilin*; Sun Qihang; Yang, Jun; Shen, Zhiquan. Fabrication of magnetic thin films by a layer-by layer self-assembly approach. Journal of Physical Chemistry C, 2009, 113, 16884-16895.

3.    Tang, Jianbin; Shen, Youqing*; Radosz, Maciej; Sun, Weilin. Isothermal Carbon Dioxide Sorption in Poly(ionic liquid)s. Industrial & Engineering Chemistry Research, 2009, 48(20), 9113-9118.

4.    Guo, Liping; Wang, Congmin; Zhao, Wenjia; Li, Haoran*; Sun, Weilin; Shen, Zhiquan. Copolymerization of CO2 and cyclohexene oxide using a lysine-based (salen)CrIIICl catalyst. Dalton Transactions, 2009, (27), 5406-5410. 

5.    Wu, Guangming; Chen, Yaofeng; Xu, Duan-Jun; Liu, Jia-Chu; Sun, Weilin*; Shen, Zhiquan. Synthesis and molecular structure of a tetrameric neodymium-silsesquioxane cage complex: {[(i-C4H9)7(Si7O12)Nd]4NaCl}. Journal of Organometallic Chemistry, 2009, 694(9-10), 1571-1574.

6.    Wu, Guangming; Sun, Weilin*; Shen, Zhiquan. Tetrahydrosalen-stabilized, chloride-containing rare-earth complexes: facile initiator precursors for the preparation of hydroxytelechelic poly( -caprolactone)s. Journal of Applied Polymer Science, 2009, 112(1), 557-562.

7.    Xi, Xiujuan; Liu, Guangxuan; Lu, Wei; Jiang, Liming*; Sun, Weilin; Shen, Zhiquan. Optically active copolymers of N-(oxazolinyl)phenylmaleimides with methyl methacrylate: Synthesis and chiral recognition ability. Polymer, 2009, 50(2), 404-409.

8.    Yu, JianFang; Wu, Guangming; Huang, Jing; Sun, Weilin*; Shen, Zhiquan. Poss-neodymium complex as precursor for polymerization of isoprene. Chinese J. of Poly. Sci., 2009, 27, 4, 597-600.

9.    Lin, Weihong; Sun, Weilin*; Yang, Jun; Shen, Zhiquan. Preparation and Magnetic Properties of Multilayer Films Based on Self-Assembly. Journal of Physical Chemistry C, 2008, 112(46), 18217-18223.

10.    Zheng, Renhua; Jiang, Huajiang; Sun, Weilin*; Yang, Jun. Synthesis and magnetic properties of novel fully conjugated polymeric complexes containing 1,10-phenanthroline. Journal of Applied Polymer Science, 2008, 110(4), 2498-2503.

11.Lin, Weihong; Sun, Weilin*; Yang, Jun; Shen, Zhiquan. Preparation and Magnetic Properties of Novel Supramolecular Polymeric Complexes Containing Bithiazole Rings. Journal of Applied Polymer Science, 2008, 110(3), 1714-1722.

12.Lin, Weihong; Sun, Weilin*; Yang, Jun; Shen, Zhiquan. Preparation and magnetic properties of novel supramolecular complexes containing bithiazole rings. Materials Chemistry and Physics, 2008, 112(2), 617-623.

13.    Yang, Jun; Lin, Weihong; Sun, Weilin*; Shen, Zhiquan. Properties of comb-likecopolymeric complexes based on thiazole ring and ionic liquid. Journal of Polymer Science, Part A: Polymer Chemistry, 2008, 46(15), 5123-5132.

14.    Xi, Xiujuan; Lou, Liping; Jiang, Liming*; Sun, Weilin; Shen, Zhiquan.   Poly(N-phenylmaleimides) bearing chiral oxazolinyl pendant: Supramolecular aggregation and enantioselectivity in fluorescence response. Polymer, 2008, 49(8), 2065-2070.

15.    Gao, Hongzhou; Yang, Jun; Sun, Weilin*; Shen, Zhiquan. Synthesis and magnetic properties of bithiazole-based polyamide complexes. Journal of Applied Polymer Science, 2008, 108(1), 554-557.

16.    Wu, Guangming; Sun, Weilin*; Shen, Zhiquan. Facile one-pot synthesis of end-capped poly( -caprolactone)s by in situ initiators from carbonyl compounds and lanthanide borohydrides. Reactive & Functional Polymers, 2008, 68(3), 822-830.

17.    Lou, Liping; Jiang, Liming*; Sun, Weilin; Shen, Zhiquan. A novel optically active diblock copolymer composed of poly(ethylene glycol) and poly[N-{o-(4-phenyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl}maleimide]: synthesis, micellization behavior, and chiroptical property. Journal of Polymer Science, Part A: Polymer Chemistry, 2008, 46(3), 1025-1033.

18.    Lin, Weihong; Sun, Weilin*; Shen, Zhiquan. Synthesis and magnetic properties of novel polymeric complexes containing bithiazole rings. Polymers for Advanced Technologies, 2007, 18(12), 959-962.

19.    Xi, Xiujuan; Jiang, Liming*; Sun, Weilin; Shen, Zhiquan. Metal-induced supramolecular chirality in optically active polymers of oxazoline-substituted N-phenylmaleimides. Chirality, 2007, 19(7), 521-527.

20.Xu, Xiaoqin; Wang, Congmin; Li, Haoran*; Wang, Yong; Sun, Weilin; Shen, Zhiquan. Effects of imidazolium salts as cocatalysts on the copolymerization of CO2 with epoxides catalyzed by (salen)CrIIICl complex. Polymer, 2007, 48(14), 3921-3924.

21.    Lou, Liping; Jiang, Liming*; Liu, Jianzhao; Sun, Weilin; Shen, Zhiquan.   Synthesis and characterization of optically active star-shaped poly (N-phenylmaleimide)s with a calixarene core. Polymer International, 2007, 56(6), 796-802.

22.Jiang, Liming*; Sun, Weilin; Kim, Jungahn. Preparation and characterization of -functionalized polystyrene-magnetite nanocomposites. Materials Chemistry and Physics, 2007, 101(2-3), 291-296.

23.    Zhang, Rui; Yang, Jun; Sun, Weilin*; Shen, Zhiquan. Synthesis and characterization of poly[4-(2-thiazolylazo)phenyl methacrylate]-co-poly(methyl methacrylate). Journal of Applied Polymer Science, 2007, 103(4), 2152-2157.

24.    He, Bingjing; Sun Weilin*; Wang, Miao; Shen, Zhiquan. New magnetic phenomena of rare earth ions-modified carbon nanotubes. Materials Chemistry and Physics, 2006, 95(2-3), 202-205.

25.    He, Bingjing; Wang, Miao; Sun, Weilin*; Shen, Zhiquan. Preparation and magnetic property of the MWNT-Fe2+ composite. Materials Chemistry and Physics, 2006, 95(2-3), 289-293.

26.    Zhou, Zhuxian; Sun, Weilin*; Tang, Jianbin; Shen, Zhiquan. Synthesis of novel copolymers containing tri(ethylene oxide) segments and bithiazole rings on the backbone and magnetic properties of their complexes. Polymer, 2006, 47(18), 6280-6284.

27.    Yang, Jun; Sun, Weilin*; Zhou, Zhuxian; Shen, Zhiquan. Synthesis and properties of polymeric complexes containing bithiazole rings and carbazole units.    Journal of Applied Polymer Science, 2006, 101(1), 443-446.

28.    Xi, Xiujuan; Jiang, Liming*; Ling, Jun; Sun, Weilin; Shen, Zhiquan.   Synthesis of star-shaped poly(-caprolactone) by samarium-based tetrafunctional initiator and its dilute-solution properties. Journal of Applied Polymer Science, 2006, 102(1), 175-182.

29.    Zheng, Ping; Sun, Weilin*; Shen, Zhiquan. Synthesis and magnetic properties of novel complexes of poly(N-2-thiazolylmethacrylamide) with Nd(III), Pr(III), and Sm(III). Journal of Applied Polymer Science, 2006, 100(2), 1289-1293.

30.    Jiang, Huajiang; Sun, Weilin*; Zheng, Renhua. Synthesis and magnetic properties of novel containing 1,10-phenanthroline polymeric complexes.  European Polymer Journal, 2006, 42(2), 425-433.

31.    Tang, Jianbin; Tang, Huadong; Sun, Weilin; Radosz, Maciej; Shen, Youqing*.   Low-pressure CO2 sorption in ammonium-based poly(ionic liquid)s. Polymer, 2005, 46(26), 12460-12467.

32.    Tang, Jianbin; Tang, Huadong; Sun, Weilin; Radosz, Maciej; Shen, Youqing*.   Poly(ionic liquid)s as new materials for CO2 absorption. Journal of Polymer Science, 2005, 43(22), 5477-5489.

33.    Tang, Jianbin; Tang, Huadong; Sun, Weilin; Plancher, Henry; Radosz, Maciej; Shen, Youqing*. Poly(ionic liquid)s: a new material with enhanced and fast CO2 absorption. Chemical Communications (Cambridge, United Kingdom), 2005,   (26), 3325-3327. 

34.    Lu, Yanbing; Sun, Weilin*; Shen, Zhiquan. Polymerization of N-phenylmaleimide with a rare-earth coordination catalyst. Journal of Applied Polymer Science, 2005, 96(4), 979-982.

35.    Tang, Jianbin; Sun Weilin; Tang Huadong; Radosz, Maciej; Shen, Youqing. Enhanced CO2 Absorption of Poly (ionicliquid)s. Macromolecules, 2005, 38(6), 2037-2039.

36.    Yang, Jun; Sun Weilin*; Jiang Huajiang; Shen Zhiquan. Synthesis and properties of two novel poly (Schiff base)s and their rare-earth complexes. Polymer, 2005, 46,10478-10483.

37.    Zhou Zhuxian; Sun, Weilin*; Yang, Jun; Tang, Jiangbin; Shen, Zhiquan. Synthesis and properties of novel fully conjugated polymers containing bithiazole rings. Polymer, 2005, 46, 9495-9500.

38.    Zheng, Ping; Jiang, Liming; Sun, Weilin*; Shen, Zhiquan. Synthesis and magnetic properties of novel poly(N-2-thiazolyl(meth)acrylamide)-Fe(II) complexes.Journal of Applied Polymer Science, 2005, 98(1), 83-87.

39.    Jiang, Liming; Sun, Weilin*. A novel bithiazole-containing polymeric complex with soft ferromagnetism. Polymers for Advanced Technologies, 2005, 16(8), 646-649.

40.Sun, Weilin*; Liu, Shuang; He, Bingjing; Tang, Jianbin; Shen, Zhiquan. New magnetic phenomena of rare earth polymerc complexes. Physics Letters A, 2004, 328, 463-466.

41.    Tang, Jianbin; Jiang, Liming; Sun, Weilin*; Shen, Zhiquan. Synthesis of poly(thiazole-2,4-diyl)-rare-earth complexes and their magnetic properties. Reactive and Functional Polymers, 2004, 61, 405-409.

42.    Liu, Shuang; Sun, Weilin*; He, Bingjing; Shen, Zhiquan. Synthesis and properties of oligomers containing substituted bithiazole rings. European Polymer Journal, 2004, 40(9), 2043-2051.

43.    He, Bingjing; Sun, Weilin*; Wang, Miao; Shen, Zhiquan. Synthesis and magnetic property of a novel SWNT-poly(Schiff base)-Nd3+ complex. Materials Chemistry and Physics, 2004, 87(1), 222-226.

44.    Liu, Shuang; Sun, Weilin*; Liu, Zhichao; Shen, Zhiquan. Synthesis and magnetic properties of polymeric complexes containing substituted bithiazole rings.    Materials Chemistry and Physics, 2004, 86(2-3), 307-310.

45.    Lin, Caiping; Sun, Weilin*; Jiang, Liming; Wang, Liqun; Shen, Zhiquan.   Bithiazole-containing polymeric complex and PVA composite film: Preparation and magnetic properties. Journal of Applied Polymer Science, 2004, 93(3), 1264-1270.

46.    He, Bingjing; Sun, Weilin*; Wang, Miao; Liu, Shuang; Shen, Zhiquan.   Preparation and characterization of a series of novel complexes by single-walled carbon nanotubes (SWNTs) connected poly(amic acid) containing bithiazole ring.    Materials Chemistry and Physics, 2004, 84(1), 140-145.

47.    He, Bingjing; Sun, Weilin*; Wang, Miao; Liu, Shuang; Shen, Zhiquan.   Preparation and characterization of a series of novel complexes by single-walled carbon nanotubes (SWNTs) connected poly(amic acid) containing bithiazole ring.    Materials Chemistry and Physics, 2004, 84(1), 140-145.

48.    Sun, Weilin*; Weng, Jian; Jiang, Lingming; Shen, Zhiquan. Study on syntheses and magnetic properties of novel bithiazole-containing polymeric complexes, Synth. Met., 2003, 137, 1341-1343.

49.    Sun, Weilin*; Jiang, Liming; Weng, Jian; He, Bingjing; Cen, Dequan; Shen, Zhiquan. A novel bithiazole-tetrathiapentalene polymer and its metal complexes.    Reactive & Functional Polymers, 2003, 55(3), 249-254.

50.    Sun, Weilin*; Jiang, Liming; Weng, Jian; He, BingJing; Shen, Zhiquan.   Bithiazole based polymer and its ferro complex containing hexacyanoferrate(III) group: synthesis and ferromagnetic property. Materials Chemistry and Physics, 2003, 78(3), 676-683.

51.    Jiang, Liming; Sun, Weilin*; Weng, Jian; Shen, Zhiquan. Novel bithiazole oligmer containing C60 and its ferro-complexes: Synthesis and magnetic properties. Polymer, 2002, 43, 1563-1566.

52.    Lu, Yanbing; Sun, Weilin*; Shen, Zhiquan. Copolymerization of N-phenylmaleimide with styrene by rare earth coordination catalyst. European Polymer Journal, 2002, 38(7), 1275-1279.

53.    Weng, Jian; Jiang, Liming; Sun, Weilin*; Shen, Zhiquan. Synthesis and magnetic properties of novel complexes of polymer containing bithiazole ring and salicylic acid. Polymer, 2001, 42, 5491-5494.

54.    Weng, Jian; Sun, Weilin*; Jiang, Liming; Shen, Zhiquan. Syntheses and magnetic properties of novel bithiazole-containing polymeric complexes. Journal of Applied Polymer Science, 2001, 81(6), 1353-1359.

55.    Weng, Jian; Sun, Weilin*; Jiang, Liming; Shen, Zhiquan. Synthesis and magnetic properties of novel poly(schiff base)-Fe2+ complexes. Macromol. Rapid Commun., 2000, 21(15),1099.

 

 

 



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