张兴宏 教授

日期:2010-11-21 23:11


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个人简介

 浙江大学高分子科学与工程学系教授,博士,博士生导师。现任高分子科学研究所副所长。近年来作为项目负责人主持国家自然科学基金项目4项,中国博士后自然科学基金一等资助项目1项,浙江省杰出青年基金1项,浙江省自然科学基金项目1项;浙江省科技厅社会公益技术项目1项;承担香港建滔化工集团、德国巴斯夫和河南天冠集团等委托的国内外研究课题多项Accounts of Chemical Research, Angewandte Chemie International Edition, Chemical Science,Macromolecules, Polymer Chemistry, Macromolecular Rapid Communications, Journal of polymer science Part A: Polymer Chemistry, Polymer 等国内外期刊发表 SCI论文60余篇,授权中国发明专利20项,授权美国专利2项受邀在Accounts of Chemical Research(IF=22)Polymer上发表专题综述,总结了在C1可控共聚领域的进展.

工作研究领域

1) 催化C1单体可控聚合

非均相催化二氧化碳与环氧化物共聚合成可降解聚碳酸酯,近年扩展到其它碳一单体如二硫化碳、硫氧化碳与环氧化物的共聚研究,合成聚硫代碳酸酯。

2) 高分子力反应化学

大分子的力化学响应行为研究。

3) 高性能热固性树脂及其复合材料

微纳米结构及其功能化的热固性树脂。

4) 3D打印基础与应用研究

联系方式

电话:0571-87953732
电子信箱:xhzhang@zju.edu.cn

个人主页

http://xhzhang.polymer.cn/

博士后招聘:

  因科研工作需要,本组拟面向海内外招聘博士后,共同合作开展高分子合成化学(一碳单体聚合及催化剂)和高分子机械力化学等研究。

应聘要求:

1. 新近毕业的博士研究生(2年内)

2. 具备良好的团队合作意识、吃苦耐劳精神、沟通协调能力和浓厚科研兴趣

待遇:

1. 课题组提供科研业绩奖和团队年终奖, 高水平博士后:年薪20+奖励;

2. 出站博后可申请浙江大学技术研发及知识转化系列或教师系列的技术职务;

3. 享受浙江大学对于博士后人员的相关政策待遇 (浙大发人〔201719号),详见:

http://hr.zju.edu.cn/postdoctor/redir.php?catalog_id=68087&object_id=77728

应聘方式:请将申请材料发至:xhzhang@zju.edu.cn

申请资料应包括个人简历、发表论文清单、研究兴趣的简要陈述和拟开展的研究内容。

(本招聘长期有效)

2018年发表文章

1. Lan-Fang Hu, Cheng-Jian Zhang, Hai-Lin Wu, Jia-Liang Yang, Bin Liu, Han-Yi Duan, and Xing-Hong Zhang*, Highly Active Organic Lewis Pairs for the Copolymerization of Epoxides with Cyclic Anhydrides: Metal-Free Access to Well-Defined Aliphatic Polyesters, Macromolecules 2018, 51, 3126−3134

2. Cheng-Jian Zhang, Hai-Lin Wu, Yang Li, Jia-Liang Yang, Xing-Hong Zhang*. Precise synthesis of sulfur-containing polymers via cooperative dual organocatalysts with high activity, Nat. Commun., 2018, 9, 2137.

3. Yang Li, Ying-Ying Zhang, Lan-Fang Hu, Xing-Hong Zhang∗, Bin-Yang Du, Jun-Ting Xu. Carbon dioxide-based copolymers with various architectures, Prog. Polym. Sci., 2018, 82, 120–157.

4. Cheng-Jian Zhang, Jia-Liang Yang, Lan-Fang Hu, Xing-Hong Zhang*, Anionic Copolymerization of Carbonyl Sulfide with Epoxides via Alkali Metal Alkoxides, Chin. J. Chem. 2018, 36, 625-629.(受邀)

5. Yang Li, Ying-Ying Zhang, Bin Liu, and Xing-Hong Zhang* HCAII-inspired Catalysts for Making Carbon Dioxide-based Copolymers: The Role of Metal-hydroxide Bond. Chinese J. Polym. Sci., 2018, 36, 139−148.(受邀)

6. Jia-Liang Yang, Xiao-Han Cao, Cheng-Jian Zhang, Hai-Lin Wu and Xing-Hong Zhang.* Highly Efficient One-Pot Synthesis of COS-Based Block Copolymers by Using Organic Lewis Pairs, Molecules 2018, 23, 298.(受邀)

 

2017年发表文章

1. Yang, J.L.,Wu, H.L.,Li, Y.,Zhang, X.H.*Darensbourg, D. J.*. Perfectly Alternating and Regioselective Copolymerization of Carbonyl Sulfide and Epoxides by Metal-Free Lewis Pairs. Angewandte Chemie International Edition 2017,56(21): 5774-5779.

2. Duan, H.Y.,Wang, Y.X.,Wang, L.J.,Min, Y.Q.,Zhang, X.H*.Du, B.Y.* An Investigation of the Selective Chain Scission at Centered Diels–Alder Mechanophore under Ultrasonication. Macromolecules 2017,50(4): 1353-1361.

3. Liu, Bin,Wang, Ya-Ling,Bai, Wei,Xu, Jun-Ting,Xu, Zhi-Kang,Yang, Ke,Yang, Yong-Zhen,Zhang, Xing-Hong*,Du, Bin-Yang. Fluorescent linear CO2-derived poly(hydroxyurethane) for cool white LED. Journal of Materials Chemistry C 2017,5(20): 4892-4898.

2016年发表文章

1. Luo, M.; Zhang, X.H.*Darensbourg, D. J.* Poly(monothiocarbonate)s from the Alternating and Regioselective Copolymerization of Carbonyl Sulfide with Epoxides. Accounts of Chemical Research  2016, 49, 2209-2219.

2.  Wu, H.L.,Yang, J.L.,Luo, M.,Wang, R.Y.,Xu, J.T.,Du, B.Y.,Zhang, X.H.*Darensbourg, Donald J.* Poly(trimethylene monothiocarbonate) from the Alternating Copolymerization of COS and Oxetane: A Semicrystalline Copolymer. Macromolecules 2016,49,8863-8868.

3.  Liu, B.; Zhang, Y.Y.; Zhang, X.H.*; Du, B.Y.; Fan, Z.Q. Fixation of carbon dioxide concurrently or in tandem with free radical polymerization for highly transparent polyacrylates with specific UV absorption. Polymer Chemistry 2016, 7, 3731-3739.

4. Luo, M.; Zhang, X.H.*;Darensbourg, D. J.* Synthesis of cyclic monothiocarbonates via the coupling reaction of carbonyl sulfide (COS) with epoxides. Catalysis Science & Technology 2016, 6, 188-192.

5. Luo, M.; Li, Y.; Zhang, Y.Y.; Zhang, X.H.*. Using carbon dioxide and its sulfur analogues as monomers in polymer synthesis. Polymer 2016, 82, 406-431.

6.Wang, L.-J.; Zhou, X.-J.;  Zhang, X.-H.*; Du, B.-Y*. Enhanced Mechanophore Activation within Micelles. Macromolecules 2016, 49, 98-104.

 

2015年发表文章

1. Li, Y.; Hong, J.; Wei, R.; Zhang, Y.; Tong, Z.; Zhang, X*.; Du, B.; Xu, J.; Fan, Z. Highly efficient one-pot/one-step synthesis of multiblock copolymers from three-component polymerization of carbon dioxide, epoxide and lactone. Chemical Science 2015, 6, 1530-1536.  

2. Min, Y. Q.; Huang, S. Y.; Wang, Y. X.; Zhang, Z. J.; Du, B. Y.; Zhang, X. H*; Fan, Z. Q. Sonochemical Transformation of Epoxy-Amine Thermoset into Soluble and Reusable Polymers. Macromolecules 2015, 48, 316-322.                

3. Zhang, X.-H*.; Wei, R.-J.; Zhang, Y. Y.; Du, B.-Y.; Fan, Z.-Q. Carbon Dioxide/Epoxide Copolymerization via a Nanosized Zinc–Cobalt (III) Double Metal Cyanide Complex: Substituent Effects of Epoxides on Polycarbonate Selectivity, Regioselectivity and Glass Transition Temperatures. Macromolecules 2015, 48, 536-544. 

4. Zhang, Y.-Y.; Wei, R.-J.; Zhang, X.-H*.; Du, B.-Y.; Fan, Z.-Q. Efficient solvent-free alternating copolymerization of CO2 with 1, 2-epoxydodecane and terpolymerization with styrene oxide via heterogeneous catalysis. Journal of Polymer Science Part A: Polymer Chemistry 2015, 53, 737-744.   

5. Zhang, Y. Y.; Li, Y.; Zhou, X. J.; Zhang, X. H*.; Du, B. Y.; Fan, Z. Q. Synthesis of an Amphiphilic Brush Copolymer by a Highly Efficient “Grafting onto” Approach via CO2 Chemistry. Macromolecular Rapid Communications 2015, 36, 852-857.

6. Luo, M.; Zhang, X.-H*.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Well-defined high refractive index poly(monothiocarbonate) with tunable Abbe's numbers and glass-transition temperatures via terpolymerization. Polymer Chemistry 2015, 6, 4978-4983

7.  Luo, M.; Zhang, X.-H*.; Darensbourg, D. J.* An Investigation of the Pathways for Oxygen/Sulfur Scramblings during the Copolymerization of Carbon Disulfide and Oxetane. Macromolecules 2015, 48, 5526-5532. 

8.  Luo, M.; Zhang, X.-H*.; Darensbourg, D. J.* An Examination of the Steric and Electronic Effects in the Copolymerization of Carbonyl Sulfide and Styrene Oxide. Macromolecules 2015, 48, 6057-6062.

9. Luo, M.; Zhang, X.-H*.; Darensbourg, D. J.* Highly regioselective and alternating copolymerization of carbonyl sulfide with phenyl glycidyl ether. Polymer Chemistry 2015, 6, 6955-6958.

2014年发表文章

 

1. Luo, M.; Zhang, X.-H*.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Alternating copolymerization of carbonyl sulfide and Cyclohexene Oxide catalyzed by zinc–cobalt double metal cyanide complex. Polymer 2014, 55, 3688-3695. 

2. Wei, R.-J.; Zhang, X.-H*; Zhang, Y.-Y.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Functional poly (carbonate-co-ether) synthesis from glycidyl methacrylate/CO2 copolymerization catalyzed by Zn–Co (iii) double metal cyanide complex catalyst. RSC Advances 2014, 4, 3188-3194. 

3. Wei, R.-J.; Zhang, Y.-Y.; Zhang, X.-H*.; Du, B.-Y.; Fan, Z.-Q. Regio-selective synthesis of polyepichlorohydrin diol using Zn–Co (iii) double metal cyanide complex. RSC Advances 2014, 4, 21765-21771. 

4. Zhang, Y.-Y.; Zhang, X.-H.*; Wei, R.-J.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Synthesis of fully alternating polycarbonate with low T g from carbon dioxide and bio-based fatty acid. RSC Advances 2014, 4, 36183-36188. 

5.Hong, J. L.; Zhang, X. H.*; Wei, R. J.; Wang, Q.; Fan, Z. Q.; Qi, G. R. Inhibitory effect of hydrogen bonding on thermal decomposition of the nanocrystalline cellulose/poly (propylene carbonate) nanocomposite. Journal of Applied Polymer Science 2014, 131.
 

2013年发表文章

1. Ren-Jian Wei, Xing-Hong Zhang*, Bin-Yang Du, Zhi-Qiang Fan, Guo-Rong Qi, Highly active and selective binary catalyst system for the coupling reaction of CO2 and hydrous epoxides, Journal Molecular Catalysis A: Chemical, 2013, 379, 38– 45.

2. Ren-Jian Wei, Xing-Hong Zhang*, Bin-Yang Du, Zhi-Qiang Fan, Guo-Rong Qi, Highly regioselective and alternating copolymerization of racemic styrene oxide and carbon dioxide via heterogeneous double metal cyanide complex catalyst, Macromolecules, 2013, 46, 3693−3697.

3. Ren-Jian Wei, Xing-Hong Zhang*, Bin-Yang Du, Zhi-Qiang Fan, Guo-Rong Qi,  Selective production of poly(carbonate-co-ether) over cyclic carbonate for epichlorohydrin and CO2 copolymerization via heterogeneous catalysis of Zn-Co (III) double metal cyanide complex, Polymer, 2013, 54, 6357-6362.

4. Ren-Jian Wei, Xing-Hong Zhang*, Bin-Yang Du, Zhi-Qiang Fan, Guo-Rong Qi,  Synthesis of bis(cyclic carbonate) and propylene carbonate via a one-pot coupling reaction of CO2, bisepoxide and propylene oxide, RSC Advances, 2013, 3,17307-17313.

5. Ming Luo, Xing-Hong Zhang*, Bin-Yang Du, Qi Wang, Zhi-Qiang Fan, Regioselective and alternating copolymerization of carbonyl sulfide with racemic propylene oxide, Macromolecules, 2013, 46, 5899−5904.

 

参加会议

2015年 全国高分子学术论文报告会 (苏州,口头报告) 

2013 IUMRS 国际先进材料会议 (青岛,口头报告)

2013年 全国高分子学术论文报告会 (上海,口头报告)


    

 



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